2020 年 69 巻 7 号 p. 703-710
A series of gemini quaternary ammonium surfactants containing carboxylate counterion with the formula C17H35CONH(CH2)2N+(CH3)2(CH2)2N+(CH3)2(CH2)2 NHCO C17H35·2Y (Y=HCOO–, CH3COO–, CH3CHOHCOO–) have been synthesized by a counterion conversion process and characterized by Fourier transform infrared spectroscopy and mass spectroscopy. It is found that these surfactants reduce the surface tension of water to a minimum value of 26.78 mN·m–1 at a concentration of 1.21 ×10–5 mol·L–1. TEM images reveal that aggregates with vesicles or tubular structure are spontaneously formed in these surfactants aqueous solution with the concentration of 1×10–3 mol·L–1. It is also found that they are effective corrosion inhibitors for A3 steel in acid solution and have superior antibacterial activity at a concentration of 0.1g·L–1.
