The kinetics data of H2O2 decomposition in aqueous solution of pH 3-4 yield great scatter and poor reproducibility. This study was performed to examine the pH dependency of ferric ion-catalyzed decomposition of H2O2. All reactions were conducted under atmospheric pressure at the temperature range of 10-30°C by using solutions of iron chloride, iron sulfate, and alum, respectively, as catalysts. Hydrochloric acid or an aqueous solution of sodium hydroxide was added to the H202 solution as .a pH adjuster prior to the decomposition reaction. In the pH range of 1-2. 9, the decomposition rate of H2O2 obeys the rate equation(l), where k· = rate constant and f = the concentration of the total iron ions. In the range pH > 2.9, the decomposition rate decreases with increased pH value. Furthermore, in this pH range, the rate does not obey the rate equation(2) into which the term for the hydrolysis of ferric ion is added, where kH = hydrolysis constant of Fe3+ The activation energy of the decomposition of H2O2 is 30 Kcal/mole for the reactions with an H2O2 aqueous solution of pH<2.5. In the case of H2O2 solution of pH>2.5, it becomes 20 Kcal/mole. The frequency factor changes in the same manner to an extent of 1010. These results lead to the following conclusions: (1) the decomposition mechanism of H2O2 in the solution with pH>2.5 is considered to be different from that in solution with pH.<2.5; and (2) the kinetics experiments for school science should be performed using the H2O2 solutions with a pH value of 1-2.
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