On the decomposition of anionic surfactants on the soil, some experiments were developed as a subject matter for environmental education. As the anionic surfactants, sodium dodecylsulfate (SDS) and sodium linear alkylbenzenesulfonate (LAS) were used; as test soil, sea sand, red-yellow soil and humus rich soil were used. Fifty grams of test soil was added into 500ml of the surfactant solution (initial concentration: 50mg/l) and the mixture was incubated in a water bath controlled at the temperature of 30°C. The change in the surfactant concentration of the solution was measured by the colorimetric method. From the experimental results, the following facts were clarified. (1) Concerning the decomposing ability of soil, we have humus rich soil, red-yellow soil and sea sand in order of decrease. (2) SDS was readily decomposed, compared with LAS. (3) The decomposition rate of LAS by humus rich soil decreased remarkably by sterilization of the soil. This shows that the biochemical action of microorganisms in humus rich soil contributes to the degradation of surfactants. (4) The decomposition rate of SDS by the sea sand, which was treated with nitric acid or sodium hydroxide solution, decreased significantly. From this, it is clear that the chemical degradation of the surfactants occurred on the surface of the soil. The reagents used are low in price, and precious instruments are not used in these experiments. The procedures are simple and can be easily performed by secondary school students. When these experiments are carried out, they can fully recognize the importance of environmental protection and the great ability of self-purification of pollutants in nature itself. From the results and discussion mentioned above, we can conclude that our experiments can be considered a valuable subject matter for environmental education in the secondary school level.
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