Geochemical gains and losses for four types of hydrothermal alteration zones distributed in lacustrine sediments of the Quaternary Sunagohara Formation, all of which have been formed under presently active Okuaizu geothermal system, were studied. Least altered (LA) zone, characterized by fresh volcanic glass, is thought to have precursory composition. Smectite-zeolite (SZ) zone, characterized by smectite, clinoptilolite and mordenite, shows gains of Si, S, Cs, As and Sb, and losses of Mn, Mg, P, Cu, Zn V and Tb. Mixed-layered clay mineral (ML) zone, characterized by illite-smectite mixed layered minerals and K-feldspar, shows gains of K, S, Rb, Cs, As, Sb Cu and Tb, and losses of Fe, Mn, Mg, Ca, Na, P, Pb, Zn and V. Kaolinite (K) zone, characterized by abundant kaolinite, shows gains of S, As, Sb and Co, and losses of Mn, Mg, Ca, Na, K, Rb, Y and Zn. Gains and losses of these components basically correspond to the following observations on the alteration minerals in this area. Addition of hydrothermal silica minerals in the SZ and ML zones, decomposition of plagioclase in ML zone, replacement of volcanic glass to clay minerals and zeolites in the SZ zone, replacement of volcanic glass to clay minerals and K-feldspar in the ML zone, precipitation of pyrite and epithermal element-rich sulfide in the ML zone, and replacement of volcanic glass and plagioclase to kaolinite in the K zone.
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