This investigation was made to evaluate the inhibiting effect of mercaptobenzothiazol (MBT) on the corrosion of copper and brass in non-oxidizing acid solution containing oxygen or oxidizing agent such as Fe
3+ or Cu
2+. The results obtained are as follows.
(1) MBT gives good inhibition to the corrosion of copper and brass in HCl, H
2SO
4 or H
3PO
4 each containing oxygen. But the requisite concentration for good inhibition in HCl is higher than in H
2SO
4.
(2) Under the existence of Fe
3+, the corrosion nhibiting effect of MBT for copper and brass in H
2SO
4 is excellent, but in HCl it is less effective than in H
2SO
4. In H
3PO
4 containing Fe
3+, the inhibiting effect of MBT for brass is excellent, but the effect for copper is insufficient and is similar to the effect in HCl.
(3) Also, MBT gives good inhibition to the corrosion of copper and brass in H
2SO
4 or H
3PO
4 both containing Cu
2+.
Furthermore, the inhibiting mechanism of MBT for the corrosion of copper in H
2SO
4 or HCl has been studied by the polarization characteristics.
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