CORROSION ENGINEERING DIGEST
Online ISSN : 1884-1155
Print ISSN : 0010-9355
ISSN-L : 0010-9355
Volume 13, Issue 6
Displaying 1-7 of 7 articles from this issue
  • [in Japanese]
    1964Volume 13Issue 6 Pages 241-245
    Published: June 15, 1964
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
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  • Takashi Kobayashi
    1964Volume 13Issue 6 Pages 246-251
    Published: June 15, 1964
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
    This investigation was made to evaluate the inhibiting effect of mercaptobenzothiazol (MBT) on the corrosion of copper and brass in non-oxidizing acid solution containing oxygen or oxidizing agent such as Fe3+ or Cu2+. The results obtained are as follows.
    (1) MBT gives good inhibition to the corrosion of copper and brass in HCl, H2SO4 or H3PO4 each containing oxygen. But the requisite concentration for good inhibition in HCl is higher than in H2SO4.
    (2) Under the existence of Fe3+, the corrosion nhibiting effect of MBT for copper and brass in H2SO4 is excellent, but in HCl it is less effective than in H2SO4. In H3PO4 containing Fe3+, the inhibiting effect of MBT for brass is excellent, but the effect for copper is insufficient and is similar to the effect in HCl.
    (3) Also, MBT gives good inhibition to the corrosion of copper and brass in H2SO4 or H3PO4 both containing Cu2+.
    Furthermore, the inhibiting mechanism of MBT for the corrosion of copper in H2SO4 or HCl has been studied by the polarization characteristics.
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  • On Iron-Chromium Alloys in Maleic Acid Solution
    Kazutaka Sakiyama, Shigetarô Hayashi
    1964Volume 13Issue 6 Pages 252-256
    Published: June 15, 1964
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
    The corrosion of iron-chromium alloys containing 0-30% Cr in maleic acid solution was investigated. The results were summerized as follows;
    (1) An increase in chromium content had a favorable effect on the diminition of the active current density of the alloys. The similar results had been found in sulfuric acid and concentrated alkaline solution.
    (2) The anodic dissolution and the corrosion weight loss became larger, as the concentration increased and temperature rose.
    (3) The logarithms of time and initial current density necessary for the onset of passivity of iron showed straight-line relation.
    (4) The formation of the order lattice (Fe3Cr) in the alloys was found to be responsible for a remarkable anodic dissolution.
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  • Yoshiharu Kitamura, Jun-ichi Itô
    1964Volume 13Issue 6 Pages 256-261
    Published: June 15, 1964
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
    The corrosion of austenitic stainless steels and titanium in the aqueous solutions of several amino acid and their salts was investigated. The total immersion tests, the cell voltage-current curve method and the potentiostatic polarization curve method were adopted.
    The following experimental results were obtained: The aqueous solutions of acidic amino acids such as glutamic acid or homocysteic acid were comparatively corrosive, while neutral and basic amino acids scarcely; the corrosive behaviors of acid and basic salts of various amino acids bore some resemblance to those of acids and bases which were estimated to be freed from the salts.
    It is suggested that amino acids, which form salts with acids or bases, might have some neutralizing action on them, resulting in reduction in the corrosive effects of these salt solutions.
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  • C. R. Bishop, [in Japanese]
    1964Volume 13Issue 6 Pages 262-267
    Published: June 15, 1964
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
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  • G. R. Somerville, J. A. Lopez, J. P. McGuigan, [in Japanese]
    1964Volume 13Issue 6 Pages 267-273
    Published: June 15, 1964
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
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  • [in Japanese], [in Japanese]
    1964Volume 13Issue 6 Pages 274-275
    Published: June 15, 1964
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
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