CORROSION ENGINEERING DIGEST
Online ISSN : 1884-1155
Print ISSN : 0010-9355
ISSN-L : 0010-9355
Volume 20, Issue 2
Displaying 1-4 of 4 articles from this issue
  • [in Japanese]
    1971 Volume 20 Issue 2 Pages 59-64
    Published: February 15, 1971
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
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  • Hisatake Narasaki
    1971 Volume 20 Issue 2 Pages 65-68
    Published: February 15, 1971
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
    The amounts of corrosion loss of steels electropolished by chromic oxide-phosphoric acid bath were determined by 1, 10-phenanthroline spectrophotometry. The corrosion tests were made in 2×10-3N sulfuric acid, 1×10-3N sodium hydroxide, and 2×10-3N calcium hydroxide solution in the presence or absence of oxygen at 30°C. The amounts of corrosion in the alkaline solution were decreased to about a tenth of that in the acid solution. The tests were applied to 5×10-3M calcium sulfate solution at 30°C, as well as to the raw water drawn from the Watarase River, Gumma Pref., the main component of which was calcium sulfate. The steels were not so corroded in these solutions as the content of chromium increased.
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  • Koichiro Osozawa, Yukishige Fukase, Kozo Yokota
    1971 Volume 20 Issue 2 Pages 69-74
    Published: February 15, 1971
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
    Fe-18Cr-20Ni-2Mo alloy prepared in vacuum induction furnace by melting electrolytic iron, chromium, nickel and metallic molybdenum showed an unusually high corrosion rate (i.e. 100-200g/m2·hr), compared with the commercially produced molybdenum stainless steels, in 5 per cent sulphuric acid test designated by JIS.
    Among thirty kinds of elements added to the above alloy up to 0.1 per cent, the most beneficial in reducing the corrosion rate were rhodium, palladium, platinum, copper and lead, followed by cerium, hafnium, thorium, uranium, indium and tin. Titanium, niobium, tungsten and silver were also beneficial if added more than 0.1 per cent. No minor alloying elements tested increased the corrosion rate of the base alloy. The mechanism of the beneficial effects were discussed. It was pointed out that minor additions of tin and lead had a beneficial effect although these elements did not influence the corrosion potential and anodic polarization of the base alloy.
    By considering the characteristics of elements in melting operations and by analysing the impurities in the commercial austenitic stainless steels containing molybdenum, it is concluded that the relatively low corrosion rate of the commercially produced stainless steel in 5 per cent sulphuric acid test is attributed to the beneficial effect of residual elements, especially copper and tin.
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  • [in Japanese]
    1971 Volume 20 Issue 2 Pages 75-91
    Published: February 15, 1971
    Released on J-STAGE: November 25, 2009
    JOURNAL FREE ACCESS
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