防蝕技術
Online ISSN : 1884-1155
Print ISSN : 0010-9355
ISSN-L : 0010-9355
20 巻, 2 号
選択された号の論文の4件中1~4を表示しています
  • 岡本 剛
    1971 年 20 巻 2 号 p. 59-64
    発行日: 1971/02/15
    公開日: 2009/11/25
    ジャーナル フリー
  • 楢崎 久武
    1971 年 20 巻 2 号 p. 65-68
    発行日: 1971/02/15
    公開日: 2009/11/25
    ジャーナル フリー
    The amounts of corrosion loss of steels electropolished by chromic oxide-phosphoric acid bath were determined by 1, 10-phenanthroline spectrophotometry. The corrosion tests were made in 2×10-3N sulfuric acid, 1×10-3N sodium hydroxide, and 2×10-3N calcium hydroxide solution in the presence or absence of oxygen at 30°C. The amounts of corrosion in the alkaline solution were decreased to about a tenth of that in the acid solution. The tests were applied to 5×10-3M calcium sulfate solution at 30°C, as well as to the raw water drawn from the Watarase River, Gumma Pref., the main component of which was calcium sulfate. The steels were not so corroded in these solutions as the content of chromium increased.
  • 遅沢 浩一郎, 深瀬 幸重, 横田 孝三
    1971 年 20 巻 2 号 p. 69-74
    発行日: 1971/02/15
    公開日: 2009/11/25
    ジャーナル フリー
    Fe-18Cr-20Ni-2Mo alloy prepared in vacuum induction furnace by melting electrolytic iron, chromium, nickel and metallic molybdenum showed an unusually high corrosion rate (i.e. 100-200g/m2·hr), compared with the commercially produced molybdenum stainless steels, in 5 per cent sulphuric acid test designated by JIS.
    Among thirty kinds of elements added to the above alloy up to 0.1 per cent, the most beneficial in reducing the corrosion rate were rhodium, palladium, platinum, copper and lead, followed by cerium, hafnium, thorium, uranium, indium and tin. Titanium, niobium, tungsten and silver were also beneficial if added more than 0.1 per cent. No minor alloying elements tested increased the corrosion rate of the base alloy. The mechanism of the beneficial effects were discussed. It was pointed out that minor additions of tin and lead had a beneficial effect although these elements did not influence the corrosion potential and anodic polarization of the base alloy.
    By considering the characteristics of elements in melting operations and by analysing the impurities in the commercial austenitic stainless steels containing molybdenum, it is concluded that the relatively low corrosion rate of the commercially produced stainless steel in 5 per cent sulphuric acid test is attributed to the beneficial effect of residual elements, especially copper and tin.
  • (I) 応力腐食割れ
    松島 巌
    1971 年 20 巻 2 号 p. 75-91
    発行日: 1971/02/15
    公開日: 2009/11/25
    ジャーナル フリー
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