Effects of gas composition, temperature and alloying elements on stress corrosion cracking of mild and low alloy steels in H₂O-CO-CO₂ system were studied. Stress corrosion tests were carried out in H₂O-CO-CO₂ mixtures by using U-bend specimens. The test results were as follows. (1) Mild and low alloy steels suffered from transgranular stress corrosion cracking in H₂O-CO-CO₂ mixtures of vast ranges of CO/CO₂ ratio. (2) No stress corrosion cracking of mild steel was found in pure CO or CO₂ gases with water, respectively. But stress corrosion cracking occurred when pure grade CO contained small amount of air (0.03% CO₂). (3) Oxygen in H₂O-CO-CO₂ mixture promoted the susceptibility to stress corrosion cracking of mild steel in liquid phase. H₂S in water showed the inhibiting effect. (4) Stress corrosion cracking occurred at testing temperatures of 20, 40, and 70°C, but its susceptibility decreased over 100°C at which general corrosion was promoted. (5) Small amount of alloying elements in the steels, i.e., C, Mn, Si, Cr, Mo, Cu W, V, Ti, Nb and Al, had no prominent effect to stress corrosion cracking. But steels containing chromium more than 9% did not suffer from stress corrosion cracking. (6) This type of cracking was called stress corrosion cracking (anodic dissolution, not hydrogen embrittlement) because of the availability of cathodic protection. (7) Treatments to relieve residual stress in steels or application of steels containing chromium more than 9% may be used to prevent stress corrosion cracking.

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In corrosive media, metallic surface can generally be protected with adsorbed film of organic corrosion inhibitors. In neutral solution, more enhanced effects can be expected by high molecular-weight inhibitors which are insoluble in the media. These inhibitors should be dispersed in it. Well-dispersed ones can be easily adsorded on metallic surface, but easily depart from the surface, and they give ineffective inhibition. Diamines, such as n-dodecyl propylene diamine and n-octadecyl propylene diamine can be made more and more dispersible with the increase of mole ratio of H₂SO₃/diamine. Several diamine salts with different amounts of H₂SO₃ were selected as inhibitors and their inhibition efficiencies on mild steel were examined in NaCl aq. solution. In conclusion, hardly dispersible inhibitors were more effective than those which were easily dispersed in their own abilities or by additional surfactants in agitated solution.

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