Water-rock interaction experiments were performed using drill-core samples (diatomaceous mudstone, hardshale) from Horonobe area, Hokkaido. Experimental results show that the pH of alkaline (initial pH=9) and acidic(initial pH=5) solutions neutralized very rapidly at initial stage and subsequently pH decreased gradually. The decrease in pH is caused by the oxidation reaction of pyrite. The ratio of H
+ to SO
42- (H
+/SO
42-) which were produced by the oxidation reaction of pyrite did not accord with the analytical results which show the lower ratio (H
+/SO
42-=0.04 (mudstone), 0.005 (shale)). This indicates that most of H
+ generated by pyrite oxidation in the experiments was consumed. The consumption of H
+ by H
+-cation (alkali and alkali earth ions) exchange reaction and dissolution of feldspar can explain this difference.
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