In this study, effect of weathering on changes of leaching properties and chemical forms of heavy metals was investigated through a laboratory scale weathering experiment using several geological samples obtained from some outcrop Tatsunokuchi formation which was distributed widely in Tohoku area of Japan as a marine sedimentary layer. At the case of the weathered samples on an outcrop, Cd leached was higher than not weathered samples and above the Japanese regulation regarded Soil Contamination Countermeasures Act. Cd existed in the sample as “exchangeable fraction”, which could dissolve easiest into water. Through a laboratory scale weathering experiment using not weathered sample, the leached Cd concentration become bigger and pH of the leachate decreased dramatically. The form of Cd was changed to “exchangeable” from “residue fraction”. On the other hand, form of As was changed to “iron—oxidized fraction” and “phosphate—exchangeable fraction” from “residue fraction”. These results showed that the forms of heavy metals in the samples, in which existed as sulfide minerals, changed to diffluent forms caused by weathering. These suggested that, for the geological surveying, it must be considered that leaching properties of heavy metals change by weathering state and preservation of samples.
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