This paper describes a kinetic analysis of devolatilization rates of woody biomass by a model based upon distributed activation
energy model and calculation results of proceeding of devolatilization of woody biomass in a simple carbonizer. Weight loss during
pyrolysis of the woody biomass was measured by a TG in three different heating rates. The data of weight loss with time were
processed according to the method proposed by Miura to determine provability density functions of activation energy distribution,
f(E), and corresponding frequency factors
k0. Original method proposed by Miura cannot be adapted directly for the analysis of
devolatilization of biomass because of decreasing in the activation energy with proceeding of the devolatilization. However,
approximate activation energy distribution functions and frequency factors, with which devolatilization reaction could be well
simulated, were obtained for woody biomass by a modification of original method proposed by Miura. For woody biomass, the
provability density functions for the activation energy distribution were so different from those of coals that
f(E) could not be
expressed by a simple distribution function such as Gaussian distribution. This may correspond to the pyrolysis behaviors of the
major components of biomass such as cellulose, hemi-cellulose and lignin. Predicted and measured amounts of remaining volatile
matters in the chars were in good agreement. Thus, an optimum operation condition of a simple carbonizer was determined by a
model using the parameters obtained. Calculations show a combination of highest heating temperature of 700K, rapid heating, short
holding time, and rapid cooling is the best operating condition for a simple carbonizer in the view point of operability and energy
saving.
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