THE MICROMERITICS
Online ISSN : 2432-2075
Print ISSN : 0429-9051
ISSN-L : 0429-9051
Volume 57
Displaying 1-29 of 29 articles from this issue
Front Cover
Foreword
Special Subject I: Powder technology for the development and improvement of batteries
  • Masahiro TATSUMISAGO
    2014 Volume 57 Pages 3-10
    Published: December 10, 2013
    Released on J-STAGE: October 03, 2018
    JOURNAL OPEN ACCESS

    Recently, sulfide solid electrolytes with high Li+ ion conductivities of 10-3-10-2 S cm-1, which are comparable to those of organic liquid electrolytes, have been developed. Sulfide glass-ceramics in the system Li2S-P2S5 are promising solid electrolytes for all-solid-state lithium cells because of their high conductivity and wide electrochemical window. Sulfide electrolytes have another merit of achieving intimate solid/solid contacts by only cold-press without high-temperature sintering. All-solid-state lithium batteries using sulphide electrolytes are expected as a next-generation battery with high safety and reliability. The possible use of active materials with high capacity such as sulfur positive electrode and lithium negative electrode, which are difficult to use in a liquid electrolyte cell, is another advantage of all-solid-state batteries. Here, characterization of electrochemical performance and reaction mechanism for all-solid-state cells with the combination of sulfide glass-ceramic electrolytes and several kinds of active materials were reported. Several approaches to forming a favourable electrode-electrolyte interface were also demonstrated.

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  • Minoru OSADA, Takayoshi SASAKI
    2014 Volume 57 Pages 11-17
    Published: December 10, 2013
    Released on J-STAGE: October 03, 2018
    JOURNAL OPEN ACCESS

    The recent development of graphene has provided new possibilities and applications for truly 2D material systems. This breakthrough has opened up the possibility of isolating and exploring the fascinating properties of 2D nanosheets of inorganic layered materials, which upon reduction to single/few atomic layers, will offer functional flexibility, new properties and novel applications. There is enormous interest in building devices and functional materials based on such 2D nanosheets of different compositions to complement those from graphene. Here, we present the progress made in the properties of 2D oxide nanosheets, highlighting emerging functionalities in electronic applications.

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  • Hideki IBA
    2014 Volume 57 Pages 18-21
    Published: December 10, 2013
    Released on J-STAGE: October 03, 2018
    JOURNAL OPEN ACCESS
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  • Shuji SASABE, Yoshinori TSUJI
    2014 Volume 57 Pages 22-26
    Published: December 10, 2013
    Released on J-STAGE: October 03, 2018
    JOURNAL OPEN ACCESS

    As more and more companies handle increasingly refined high-grade products, further evolution in powder evaluation methods are essential to match the enhancement of production process and maintain quality control.

    Development of new products should evolve hand in hand with the evaluation process. The following is a report regarding our new evaluation equipment which is developed accordingly to the growing needs of powder evaluation.

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Special Subject II: Progress of powder technology supporting the pioneering technology to the fundamentals
  • Hirofumi TAKEUCHI
    2014 Volume 57 Pages 27-35
    Published: December 10, 2013
    Released on J-STAGE: October 03, 2018
    JOURNAL OPEN ACCESS

    Particulate design means particle size control or surface modification for preparing functional particles.

    Preparation of composite particles is also included in this research category. This article demonstrates recent successful results on particulate design of liposomal particles for preparing novel drug delivery systems in oral, pulmonary and ocular administration of drug. These results demonstrated that surface modification of liposomes with polymers and their particle size control can much improve the drug delivery function of liposomal carriers. Each result in particulate design research may lead to effective drug delivery and development of non-invasive drug delivery system of liposomal systems. In the research of pharmaceutical powders for solid dosage form preparation, particle design of pharmaceutical excepients can improve the compaction property in the objective powder formulation. This result demonstrated a novel preparation method of oral disintegration tablets, which is one of the most interesting dosage forms as a new category of tablet for good patient compliance.

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  • ─The Fabrication Process of Ceramic Layers Using Electrophoretic Phenomenon of Surface-Charged Colloidal Particles, “Electrophoretic Deposition”, and Example of the Application of the Process for SOFC─
    Tetsuo UCHIKOSHI
    2014 Volume 57 Pages 36-42
    Published: December 10, 2013
    Released on J-STAGE: October 03, 2018
    JOURNAL OPEN ACCESS

    Electrophoretic deposition (EPD) is a colloidal process wherein ceramic bodies are directly shaped from a stable colloid suspension by a dc electric field. Compared to other advanced shaping techniques, the EPD process is very versatile since it can be modified easily for a specific application. The EPD is also gaining increasing interest as a processing technique for production of novel inorganic nanostructured and nanoscale materials. In this paper, the deposition mechanism of the EPD process and its application on SOFC is introduced.

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  • Junichi TATAMI, Hiromi NAKANO
    2014 Volume 57 Pages 43-50
    Published: December 10, 2013
    Released on J-STAGE: October 03, 2018
    JOURNAL OPEN ACCESS

    A mechanical particle composite process was applied to develop several kinds of advanced ceramics. Nanoparticles were stuck on a larger particles and they were well dispersed in powder mixtures. In most cases, microstructure of the developed advanced ceramics was very uniform. CNT-TiO2 nanocomposite particles for electrically conductive CNT-dispersed Si3N4 ceramics from, AlN-Y2O3 nanocomposite paritcles for AlN ceramics having highly electrical insulation, ZnO-Al2O3 nanocomposite particle for ZnO ceramics with highly electrical conductivity, Al2O3-carbon black nanocoposite particles for pore size and morphology-controlled porous Al2O3 ceramics, and BaCO3-TiO2 nanocomposite particles for synthesis of tetragonal BaTiO3 nanoparticles having highly crystallinity were prepared by the mechanical particle composite process. It was shown that the mechanical particle composite process is very effective in the microstructure control and improvement of many kinds of properties of advanced ceramics.

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  • Junya KANO
    2014 Volume 57 Pages 51-58
    Published: December 10, 2013
    Released on J-STAGE: October 03, 2018
    JOURNAL OPEN ACCESS

    Beads motion in a stirred mill having slurry was simulated by the Discrete Element Method (DEM), enabling to calculate the impact energy of beads. The impact energy of beads is known to be well correlated with the grinding rate constant, therefore, it was monitored as an effective index of grinding performance in the simulation work. The present work is to investigate effect of the pin configuration, particularly, the number of pins attached on the agitator on the beads motion as well as the impact energy. We have found that the beads motion is dependent on the number of pins, and the impact energy reaches the maximum value at 8 in number of pins under the present condition. In addition, the maximum value under the impact energy is shifted towards large number of pins as the beads filling ratio increases. A new simultaneous simulation of dynamic and breakage behavior of particles has been developed and compared with those of experiment. The simulation results agree well with experimental ones.

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  • Hisao MAKINO, Naoki NODA
    2014 Volume 57 Pages 59-65
    Published: December 10, 2013
    Released on J-STAGE: October 03, 2018
    JOURNAL OPEN ACCESS

    Coal is very important energy resource now and for the future, because minable reserves of coal are more abundant than other fossil fuel. Powder technology is one of the most useful key technology for coal utilization from coal mining process to flue gas treatment process after coal utilization for power generation.

    In this paper, the role of powder technology in conventional pulverized coal combustion power station is introduced at first. And the development tendency of powder technology for the improvement of conventional pulverized coal combustion power station and the development and progress of higher performance new type power generation system using coal gasification process are discussed.

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  • Masahiro INOKI
    2014 Volume 57 Pages 66-73
    Published: December 10, 2013
    Released on J-STAGE: October 03, 2018
    JOURNAL OPEN ACCESS

    In recent years, the fine particle procession technology has been utilized widely in various fields such as vehicle, electronic, food, pharmaceutical and biotechnology. On the other hand, the appearance of innovative equipment is expected significantly, in order to obtain the high added value and improve the quality of the final products.

    In this paper, we introduce principle, structure, feature and experimental data on the latest powder processing machines for grinding, classification, sphericalization, compositing and drying which we developed in the past few years.

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