2018 年 67 巻 9 号 p. 1163-1169
In this study, acidic deep eutectic solvents (DESs) have been studied as catalyst in transesterification of soybean oil with methanol to produce biodiesel. p-Toluenesulfonic acid-based deep eutectic solvent (P-DES), composed of p-toluenesulfonic acid and choline chloride (1:3, mol/mol), was found to be an efficient transesterification catalyst for biodiesel production. The optimum conditions for the transesterification process were as follows: 8% P-DES catalyst, 8:1 molar ratio of methanol to oil, reaction temperature of 110°C and 2 h reaction time. The transesterification yield could reach 98.66±0.17%. And the P-DES exhibited as a heterogeneous catalyst after the reaction, which could be separated easily. And P-DES could remove the trace amount of by-product (glycerol) in the final biodiesel product, making this process more simple and cleaner.
