Purpose: The aim of this study is to observe the bonding interface in veneering porcelain bonded to two kinds of zirconia (yttria-stabilized zirconia and ceria-stabilization zirconia/alumina nanocomposite) and to examine its integrated state.
Methods: Two kinds of zirconia plates of this finished size, 20.0 (L) × 4.0 (W) × 0.4 (T) mm, were prepared. Some were pretreated by sandblast, some by heat, and some not at all. Porcelain was fired to zirconia plate with or without opaque porcelain and finished thickness of 1.6 mm. The specimen was tested by 3-point flexural testing. The fractured specimen was observed with an electron microscope to confirm the exfoliation of porcelain from the zirconia. The bonding interfaces were analyzed with an electron probe microanalyzer.
Results: The results of 3-point flexural testing were not significantly different under any condition, but the existence of exfoliation revealed a significant difference between the two kinds of zirconia (P < 0.01). The electron microscope image revealed a minute particulate change near the interface of the ceria-stabilization zirconia/alumina nanocomposite. As for element analysis at the bonding interface, no diffusion of the main ingredient elements was observed, but a diffusion-like change with oxygen was noticed.
Conclusions: As for the zirconia/porcelain composite, no difference of strength was observed under any condition. It was clear, however, that the destruction of yttria-stabilized zirconia was accompanied by exfoliation. An electron microscope image and ultimate analysis suggested the possibility of a chemical bond between porcelain and zirconia.
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