Bulletin of the Agricultural Chemical Society of Japan
Online ISSN : 1881-1272
Print ISSN : 0375-8397
ISSN-L : 0375-8397
Volume 8, Issue 10-12
Displaying 1-11 of 11 articles from this issue
  • Ryo YAMAMOTO, Yasuyosi OSIMA, Teruo GOMA
    1932 Volume 8 Issue 10-12 Pages 133-136
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
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  • Ryo YAMAMOTO, Tosiro MURAOKA
    1932 Volume 8 Issue 10-12 Pages 136-140
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
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  • Elaeocarpus serratus Lin
    Ryo YAMAMOTO, Yasuyosi OSIMA, Teruo GOMA
    1932 Volume 8 Issue 10-12 Pages 141-142
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
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  • A New Glycoside Hiviscin
    Ryo YAMAMOTO, Yasuyosi OSIMA
    1932 Volume 8 Issue 10-12 Pages 142-149
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
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  • Ryo YAMAMOTO, Tosiro MURAOKA
    1932 Volume 8 Issue 10-12 Pages 149-151
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
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  • Kotaro NISHIDA
    1932 Volume 8 Issue 10-12 Pages 151-154
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
    The chemical composition of the “Di-saké” compared with that of the ordinal “saké” is summarized as follows:
    (1) In the above experimental results the nitrogenous compounds isolated from 10 litres of “di-saké”, are hypoxanthine-hydrochloride (0.20 g.), arginine nitrate (4.60 g.), cholinechloroaurate (6.75 g.), and ammonia (3.52 g.), while the isolated bases from 25 litres of “saké” by Dr. K. Kurono, are cholinepicrate (3.8 g.), histaminepicrate (0.15 g.), lysinepicrate (0.52 g.) and ammonia (1.3 g.). It is the most great difference that the “di-saké” contains large amount of arginine, which could not be isolated from the “saké”.
    (2) As regards the general composition, 1 fined great difference between the “di-saké” and the “saké”: in the former, the quantity of reducing sugar (chiefly glucose) and other extractive substances are considerably much more than those of the latter.
    (3) In the “di-saké”, the amount of non-protein substances is much more than those of the “saké”.
    (4) The reaction of “di-saké” is almost neutral, but in the “saké” remarkably acidic.
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  • Reduction potential of p-aminoazobenzene
    Masuzo SHIKATA, Isamu TACHI
    1932 Volume 8 Issue 10-12 Pages 154-155
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
    The results of the investigation on the electrolytic reduction potential of p-aminoazobenzene with the polarograph and dropping mercury cathode at 25°C were as follows.
    (1) Reduction potential of p-aminoazobenzene was more positive in lower concentration than that in higher concentration in every PH solution.
    (2) Owing to the weak basic property of p-aminoazobenzene, there were two reduction potentials which were due to the dissociated and undissociated forms in some proper acidic solutions. In high acidic solution, p-aminoazobenzene changed to quinoid form which was demonstrated by spectrographic study. The reduction potential of quinoid form was more positive than that of azoid form and further, that of dissociated form more posi tive than that of undissociated form.
    (3) The reduction potential of p-aminoazobenzene which substituted NH2 group in azobenzene was more negative than that of the latter. This is expected from our negativity rule of electrolytic reduction.
    (4) The solubility of p-aminoazobenzene in water at 25°C was found to be 2.815•10-4g. mol per litre calculated by the result of polarographic measurement.
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  • Reduction potential of dimethylaminoazobenzene
    Isamu TACHI
    1932 Volume 8 Issue 10-12 Pages 155
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
    The results of the investigation on the electrolytic reduction potential of dimethylaminoazobenzene with the polarograph and dropping cathode were as follows:
    (1) The reduction potential of dimethylaminoazobenzene was more negative in high concentration than that of in low concentration, except in the case of solution which Pa was lower than 2.2.
    (2) In acidic solution, the reduction of dimethylaminoazobenzene showed the reduction potentials of quinoid, dissociated and undissociated forms of azoid form as same as in the case of p-aminoazobenzene.
    (3) The maximum currents of the polarograms of dimethylaminoazobenzene in acidic solutions were increased with elevation of concentration of ethanol. From these facts, we assume that dimethylaminoazobenzene becomes easily adsorbable on the mercury cathode in acidic solutions.
    (4) The•mutual relation among the reduction potentials of azobenzene, p-aminoazobenzene and dimethylaminoazobenzene was found to follow our negativity rule of electrolytic reduction, that is, reduction potential of azobenzene was most positive and that of dimethylaminoazobenzene most negative among them.
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  • Kazuo YAMAFUJI
    1932 Volume 8 Issue 10-12 Pages 156-159
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
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  • Ume TANGE
    1932 Volume 8 Issue 10-12 Pages 159-172
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
    1. It is confirmed that both linoleic acid and linolenic acid are equally effective in curing a specific deficiency disease produced by rigidly fat-free diets.
    2. Oleic acid and elaidic acid induce growth response of rats, but seem to be ineffective in curing sick rats.
    3. The rats receiving clupanodonic acid suddenly lose body weight and are not cured with either linoleic acid or linolenic acid.
    4. The poor results obtained with stearic acid may be attributed to im-perfect absorption.
    5. Vitamin B and G are definitely ruled out as a limiting factor in this dietary deficiency.
    The author wishes to express her deep gratitude to Professor U. Suzuki for his many helpful suggestions throughout this work and to Dr. W. Nakahara for his invaluable advice on the anatomical examination. She is also indebted to the Keimei Society for financial assistance.
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  • First Report. -Sterilising action of Mineral Acids
    Sogo TETSUMOTO
    1932 Volume 8 Issue 10-12 Pages 172-180
    Published: 1932
    Released on J-STAGE: November 27, 2008
    JOURNAL FREE ACCESS
    (1) Sterilising action of mineral acids such as HNO3, HCl, H3PO4 is determined by PH of each solution, and has no relation about kind of acids.
    (2) Anions of strong mineral acids have no sterilising action.
    (3) There is no special relation between the value of molecular weight of mineral acids and sterilising action.
    (4) On sterilising action of cromic acid and HCNO, PH concerns a little.
    (5) Sterilising action of dilute cromic acid and HCNO, such as N/100 are almost due to the action of undissociated acid molecule.
    (6) The violent sterilising action of Osmic acid is chiefly due to the action of its anion and PH concerns a little.
    (7) Sterilising action of Boric acid is chiefly due to PH and the strilising action of it is very feeble.
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