Journal of the Ceramic Association, Japan
Online ISSN : 1884-2119
Print ISSN : 0366-9998
ISSN-L : 0366-9998
Volume 47, Issue 554
Displaying 1-11 of 11 articles from this issue
  • ON THE RELATION BETWEEN BENTONITE AND ACID-CLAY
    Mune Utida
    1939 Volume 47 Issue 554 Pages 63-67
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    On the basis of many analytical data the author concluded that both bentonite and acid-clay or fuller's earth are quite the same clay material and they must have at least two common end minerals, montmorillonite and beidellite, in the pure sides. In other words, the BENTONITE as well as the ACID-CLAY are nothing but a rock name. Therefore they have no definite meaning in the strict mineralogical sense.
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  • [in Japanese], [in Japanese]
    1939 Volume 47 Issue 554 Pages 67-76
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • Seiji Kondo, Toshiyoshi Yamauchi, Mititane Oki
    1939 Volume 47 Issue 554 Pages 76-81
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
    A study has been made on the inversion of dicalcium silicate. Specimens for the experiments have been prepared by heating an intimate mixture of 2 mol. of c. p. calcium carbonate and 1 mol. of c. p. silica for 2 to 8 hr. at temperatures ranging between 1400 and 1700°C. They have been quenched in ice-cold mercury and have been examined for microstructure, X-ray diffraction, thermal changes, etc. with the following results:
    (1) Specimens made at 1500° and up have dusted less than those prepared at lower temperatures. All specimens quenched in ice-cold platinum crucible or in similar way have been mixtures of α-and γ dicalcium silicates.
    (2) when the temperatures have been raised gradually over 1500°, the products quenched as said above have become poorer in γ modification and richer in α one, almost pure α dicalcium silicate being obtained at about 1700°.
    (3) On cooling naturally, the products have to change completely to γ form, since α and β are only stable at 2130 to 1420° and 1420 to 675° resp. However, in facts, they have contained α form and pure γ form has never been given.
    (4) Pure γ dicalcium silicate can be obtained from its mixtures with α form (a) by screening the products to collect dusted minute powder, (b) by reheating the products long at temperatures therein γ form is stable, say over 300 hr. at 550°, and also (c) by dissolving the α form off with water.
    (5) As to thermal analysis, γ dicalcium silicate has indicated a strong endothermic reaction at 720±5° in heating up and a strong exothermic one at 690±5° in cooling down. These changes are probably due to γ_??_β inversion α 2CaO⋅SiO2 and 3CaO⋅2SiO2 have shown slight exothermal changes at temperatures between 600 and 700°; they owe probably to γ_??_β inversion of γ dicalcium silicate contamimated in the specimens.
    (6) It may be concluded that α β and α γ transformation are sluggish inversions while β γ changes are very quick and are therefore high-low inversions.
    (7) It is likely that synthetic 3CaO⋅2SiO2 contain some γ dicalcium silicate and also that we have to investigate further on the problem whether tricalcium disilicate exists or not?.
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  • [in Japanese]
    1939 Volume 47 Issue 554 Pages 82-88
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • [in Japanese]
    1939 Volume 47 Issue 554 Pages 89-91
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
  • [in Japanese]
    1939 Volume 47 Issue 554 Pages 91-94
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • 1939 Volume 47 Issue 554 Pages 95-105
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • 1939 Volume 47 Issue 554 Pages 106-113
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
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  • 1939 Volume 47 Issue 554 Pages 117
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
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  • 1939 Volume 47 Issue 554 Pages 118-119
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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  • [in Japanese], [in Japanese], [in Japanese]
    1939 Volume 47 Issue 554 Pages ap17-ap23
    Published: February 01, 1939
    Released on J-STAGE: April 30, 2010
    JOURNAL FREE ACCESS
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