Metal nitrates are readily adsorbed on alumina in organic solutions such as acetone and n-butylacetate. Adsorption isotherms for such compounds as uranyl nitrate, thorium nitrate and cerium nitrate (III) were examined, and the adsorption was found to have occured monomolecularlly on the surface of the alumina.
The weakest adsorption strength on alumina was found to be that of uranyl nitrate, and the adsorbed uranyl nitrate could be substituted very easily by other nitrates such as of fission products.
The logarithmic decrease of the Kd values of fission products on alumina with increase of uranyl nitrate concentration in n-butylacetate was found to correspond to the increase of the solubility of nitrates of fission products (Ce, Sr and Zr) with increase of uranyl nitrate concentration.
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