Oxidation behavior of the stainless steel fuel cladding is one of the important information to clarify the oxygen balance in the fast breeder reactor fuel pin during irradiation. In our previous work
(1), oxidation behavior of SUS-316 stainless steel was investigated under oxygen potentials controlled by Mo/MoO
2 and NbO
2/Nb
2O
5 oxygen buffers, and the following information was obtained : The reaction product due to oxidationwas a mixture of Cr
2O
3 and MnCr
2O
4, and the oxidation rate was controlled by the outward diffusion of Cr in stainless steel ; this diffusion process was ascribed to the grain boundary diffusion because the activation energy, calculated from the temperature dependence of the parabolic rate constant, was close to that of the grain boundary diffusion of Cr in stainless steel rather than that of the lattice diffusion
(2).
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