The ionic processes of γ-irradiated triphenylamine (TPA) in 3-methylpentane glass (3-MP) have been studied. The thermoluminescence curve of the irradiated sample shows two maxima at 77°∼83°K and 83°∼90°K. The effects of differences in radiation dose and of time elapsed after irradiation at 77°K on the luminescence yield of these two peaks have been examined. The optical absorptions of trapped electrons (e
-t), TPA
+ and TPA
- are measured as functions of the storage time at 77°K and of the elevation of temperature. The results for IR and UV bleaching and for prolonged storage at 77°K suggest the presence of negative species other than e
-t and TPA
-. In the irradiated sample at 77°K in the presence of 10
-4∼10
-3M TPA, positive and negative species other than TPA
+ and TPA
- exist and these charges are transferred to TPA to form TPA
+ and TPA
- by warming. These behaviors of the ionic species are discussed.
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