According to recent fire statistics in Japan, number of electrical fires shows tendency to increase gradually. One of main causes of electrical fire is short-circuit. The short-circuit due to thermal degradation is one main cause though there are many other causes.
The short-circuit mechanism of PVC cords at defective heat loss was studied as following two cases :
(1)Temperature of the covering rises rapidly by joule heating etc., or (2)Temperature of the covering rises slowly by thermal degradation at comparatively low temperature for a long time, then PVC cords are short-circuited.
As a result, the followings were obtained :
1) Though PVC cord is not short-circuited in the rating current (20 A) of divergence breaker when it is extended on the straight line and there is no defective heat loss at the room temperature, wound cord is short-circuited at the allowable current of PVC cord regardless of the protection equipment such as the divergence breaker.
2) When temperature of the covering of PVC cord rises rapidly to nearly melting point by joule heat, PVC cord is short-circuited in a few minutes or less by the direct contacting with electrical wires of two poles due to softening and melting of the covering. On the other hand, when PVC cord is short-circuited due to the thermal degradation of a long term, it is short-circuited by absorbed moisture on CaCl
2 or by insulation failure due to the decrease in the insulation resistance of the covering.
3) HCl generated by thermal degradation process reacts with CaCO
3 which is added as filling of PVC covering, and hygroscopic CaCl
2 is produced. The short-circuit mechanism by absorbed moisture on CaCl
2 is expected, and the generation of CaCl
2 can be quantitatively measured.
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