The silver potentiometric titration has been tried with eighteen kinds of aza-indolizines, that is two kinds of diaza-indolizines, eleven kinds of triaza-indolizines and five kinds of tetraza-inzolines. Following results were obtained:
I. In comparison with some organic sulfur compounds, aza-indolizines generally show nobler potential at same pH.
2. Among aza-indolizines which have same substitution radical at the similer position, potential is less noble in the order of 2, 3, 7-triaza-indolizines, 2, 3, 4-triaza-indolizines and tetraza-indolizines,
3. Among 2, 3, 4-triaza-indolizine and tetraza-indolizine, compounds which have inactive radical as methyl etc. into the position of 5 and 7, do not react with silver ions. But at pH 10.0 and 11.0, the decomposition may occur because the different precipitation from that of buffer solution itself is found.
4. In triaza-indolizine, with the numbers of OH radical which is substituted the positios of 5 and 7. there are compounds which need one or two silver ions. That is to say that the compound having one OH radical reacts with silver salt at the ratio one to one and two OH radicals, one to two. While tetraza-indolizine need the silver salt in the ratio one to two even when one OH radical substitutes to the position of 5 or 7.
5. In triaza-indolizine, the effect with methyl, ethyl and phenyl radicals which substitute to the same position could not be concluded because of the shortage of example.
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