In a previous paper part III, we reported that the polarizing film of borated polyvinyl alcohol (PVA-B) was much superior to that of polyvinyl alcohol (PVA) in heat and moisture resistance property.
But we often experience that PVA-B film is torn off easily in the process of wet streching. This report discusses the wet streching condition of PVA-B film to prevent above defects, and considers the bonding state between PVA and boric acid.
Experimental discussion has brought the wet streching condition to light, that the high concentration of boric acid must be contained in streching bath and held in high temperature suitable for its concentration. About the bonding state, we have proposed net working structure as well as in dry state, bonding with boric acid on the surface of PVA film or its micell, and movement of bond by wet streching.
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