The inhibiting action of several stabilisers to the production of Ag
2S by thiourea was studied. They were 5-methyl-7-oxy-1, 2, 3, 4, 6-pentazaindene, benztriazole, 6-nitrobenzimidazole, 4-ethoxy-6-methyl-1, 3, 3a, 7-tetrazaindene, and bromotriazole. AgBr containingno gelatin was ripened with thiourea in buffer, and produced Ag
2S was analised. When stabiliser was added on the halfway of the ripening, the amounts of produced Ag
2S in the subsequent process were influenced. The experimental process were following. After ripening, unreacted AgBr dissolved by sodium thiosulfate solution was separated off from formed Ag
2S by filtration. Ag
2S thus obtained was then converted to AgNO
3 by treatment with conc.HNO
3. This silver ion estimated by electrometrical titration may be considered the measure of the inhibiting action of stabiliser. The results were following, 5-methyl-7-oxy-1, 2, 3, 4, 6-pentazaindene and benztriazole had distinct inhibiting actions, others a few or not. Comparing with the data of stabilizers to emulsions and the data of this experiments, it recognized that there are fundamental differences between reaction mechanism of pentazaindene and that of benztriazole. To stop second ripening of emulsion by stabilizer, it needs to inhibit of Ag
2S in the subsequent process.
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