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Volume 49, Issue 1
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[in Japanese]2003 Volume 49 Issue 1 Pages 1-2
Published: May 30, 2003
Released on J-STAGE: June 28, 2010
JOURNAL FREE ACCESSDownload PDF (387K) -
---For the determination of stability constants of crown compounds-metal complexes in the organic solvents saturated with waterYoshihiro Kudo2003 Volume 49 Issue 1 Pages 3-13
Published: May 30, 2003
Released on J-STAGE: March 01, 2011
JOURNAL FREE ACCESSDownload PDF (1541K) -
Hiroki HOTTA, Toshiyuki OSAKAI2003 Volume 49 Issue 1 Pages 15-30
Published: May 30, 2003
Released on J-STAGE: June 28, 2010
JOURNAL FREE ACCESSThe study of electron transfer (ET) at the oil (O)/water (W) interface is useful for understanding energy conversion processes occurring at biomembranes. The recent introduction of SECM (scanning electrochemical microscopy) as well as other new methods to this field has revitalized the study of the reaction mechanism of ET at the O/W interface. However, the mechanism is not necessarily simple, and often involves an ion-transfer process. When a not very hydrophobic complex such as ferrocene (Fc) is used for the redox species in the O phase, the ET would occur homogeneously in the W phase, the interfacial transfer of the ionic product (e.g., Fc+) being responsible for the current flowing through the interface. On the other hand, when an extremely hydrophobic complex such as lutetium bihthalocyanine is used, the heterogeneous, i.e., true ET should occur at the O/W interface. Marcus proposed a general kinetic equation for the heterogeneous ET. There are some experimental data which support the Marcus theory, however, further careful and detailed studies seem to be required. In this review, recent developments in theory and methodology in this research field are described.View full abstractDownload PDF (2485K) -
Mitsugi Senda2003 Volume 49 Issue 1 Pages 31-35
Published: May 30, 2003
Released on J-STAGE: June 28, 2010
JOURNAL FREE ACCESSA cylindrical-diffusion model to include the bimolecular-reaction effect in voltammertric theory of the electron transfer at O/W interface is proposed. Analytical expressions for pulse-voltammetric current whenm the electron transfer is of pseudo-unimolecular nature are presented.View full abstractDownload PDF (2148K) -
Hermann Berg2003 Volume 49 Issue 1 Pages 37-61
Published: May 30, 2003
Released on J-STAGE: March 01, 2011
JOURNAL FREE ACCESSDownload PDF (7696K) -
[in Japanese]2003 Volume 49 Issue 1 Pages 72
Published: May 30, 2003
Released on J-STAGE: March 01, 2011
JOURNAL FREE ACCESSDownload PDF (174K)
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