Review of Polarography
Online ISSN : 1884-7692
Print ISSN : 0034-6691
ISSN-L : 0034-6691
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Preface
Award Review Article, 2023 Shikata International Medal
  • Analytical Electrochemical Studies of Dynamic Processes at Electrode/Solution Interfaces
    Takamasa Sagara
    2024 Volume 70 Issue 1 Pages 5-14
    Published: May 22, 2024
    Released on J-STAGE: May 22, 2024
    DOIhttps://doi.org/10.5189/revpolarography.70.5
    JOURNAL FREE ACCESS
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    Entities showing dynamic processes on an electrode surface range from small molecules to millimetersized soft materials. The dynamics is driven by the potential dependence of the interaction of ions and dipoles with the electrode surface charge as well as the lateral interactions among the molecules. Regulated reversible movements of molecular assemblies at electrified interfaces result in new interfacial functions and emergent syntheses. To understand what are really changing at the electrode/solution interface while dynamic processes are undergoing, it is essential to have facile tools to analytically track the interfacial dynamics, as exemplified by potential-modulated spectroscopies. Typical dynamic behavior and spectroelectrochemical methods are broadly reviewed.

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