Velocity field in the vicinity (< 600 micro-m) of a moving contact line was measured using the particle imaging velocimetry (PIV) technique. The experiments consisted of withdrawing a solid plate of different surface materials (glass, stainless steel, acrylic resin, and a superhydrophobic coating) from water into air, or from water into polydimethylsiloxan (PDMS), at a constant rate of 0.62 mm/s. The large difference in the surface wettability in these combinations of fluid and surface materials resulted in a variation of water contact angle from zero to 130 deg. The viscous continuum theory by Huh (1971), with the contact angle and the viscosity ratio between the upper and lower fluids given as the boundary conditions, failed to reproduce the measured velocity field. When the tangential velocity on the interface was forced to be the same as the measured value, the model reproduced well the measured velocity field.
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