油化学
Online ISSN : 1884-2003
ISSN-L : 0513-398X
粒子の付着及び脱離現象によるHamaker定数の見積もり
田川 美恵子中田 由美子後藤 景子
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1989 年 38 巻 1 号 p. 88-93

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Adhesion and removal phenomena in aqueous solutions were investigated using spherical polyethylene particles and a quartz plate. The experimental results are discussed and explained on the basis of the heterocoagulation theory, using ζ-potentials of the particles and the quartz plate as determined by micro-electrophoresis. The magnitude of the energy barrier preventing particle adhesion was found to be about 4000 κT for particles of 4-5μm in diameter. The Hamaker constant (A11) of a polyethylene particle was estimated by the adhesion and removal phenomena and was determined as 6.06.8×10-13ergs from curves of interaction energy plotted against separation.
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