A thermal power plant employing amine-based post-combustion CO
2 capture (PCC) is a key technology for low-carbon, dispatchable power sources for the carbon-neutral electric power sector. Power-to-heat amine-based PCC is likely an economically promising system operation, which conducts CO
2 absorption along with the power generation and facilitates CO
2 desorption through a heat pump driven by exceptionally inexpensive electricity procured during peak power generation periods from electricity market via the grid. The combination of mathematical modelling and cost analysis evaluated the annual profits of the proposed system in future electricity markets (2030–2050) in Japan, which was predicted by an energy system optimization model. The results demonstrated that employing power to heat amine-based PCC instead of the conventional one increased the annual profits by approximately 2–27%. Notably, depending on economic factors (e.g., electricity market prices, capacity factor, or interest rate), annual profits were positive without further improvement in the amine-based PCC technologies. This result indicates that now is the time to move from laboratory investigations to real-world implementation and that techno economic analysis regarding investment decision is more important rather than calculation of carbon capture costs to showcase the feasibility of thermal power plants with PCC, propelling its swift implementation.
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