Sorption isotherms, which describe CO
2 storage capacity of rocks, are important for estimating CO
2 sequestration potential of geological reservoirs. This study examined CO
2 sorption capacity of Kimachi sandstone and Iidate granite in the CO
2 rich dense phase, the condition of which is expected to occur mostly in the course of CO
2 injection into geological reservoirs because of the displacement of formation water by CO
2 pressurization in geological reservoirs as storing CO
2 into aquifers, at geological temperature and pressure. CO
2 sorption measurements were conducted using both volumetric and gravimetric methods at temperatures of 33∼200°C and pressures up to 20MPa. It was found that Kimachi sandstone and Iidate granite were capable of sorbing CO
2 into their internal structures. At 50°C, the amount of CO
2 sorption reached the maximum value of 1.4 mmol/g (= 31.4 scc/g) for Kimachi sandstone and 0.7 mmol/g (=15.7 scc/g) for Iidate granite, respectively. Comparison among model predictions (monolayer adsorption, solubility and pore-filling) suggests that the sorption of CO
2 onto rock minerals may contribute to a significant portion of the CO
2 storage capacity in the course of CO
2 injection.
This investigation points out the significance of CO
2 sorption onto rock minerals for the possible mechanism in CO
2 geological storage.
抄録全体を表示