Flotation technique is very useful for removing residual contaminated particles in the sand fraction. Chemical scrubbing in a scrubber unit detaches contaminated particles from the surface of soil/sand particles. In a flotation unit, contaminated particles are selectively made hydrophobic by modifying their surface properties with selective flotation reagents. The hydrophobic particles are attached to air bubbles and are carried to the froth layer. The contaminated particles are scraped away with the froth layer.
The objective of this experimental study was to understand the performance and validity of soil washing system which consisted of mainly hydrocyclone and flotation processing. A variety of soils contaminated with mercury, agrichemicals (BHC and DDT), dioxins, mineral oil, and radiocesium (radio-Cs) were examined. A surface-adsorption model and dimensionless load curves of feed soils were introduced and used in analyzing characteristics of contaminant distributions in soils.
Removal ratios of hydrocyclone fluctuated greatly with contaminant distributions in feed soils. Flotation made up for the low ratios of hydrocyclone, and was able truly to improve the total ratios at high levels. The average removal ratio of hydrocyclone was 68.8%, and the average ratio was greatly improved to more than 90%, when flotation technique was employed for further treatment of hydrocyclone underflow (UF). A figure showing a relation between a recovery ratio to froth and a froth-to-UF ratio enabled us to provide a very effective way to visually grasp the flotation performance. The froth-to-UF ratios ranged at relatively high levels of 25~41 times, and the recovery ratios to froth remained at low levels below 5% for soils contaminated with dioxins, agrichemicals, and mercury. It is concluded that the flotation can work very effectively to remove contaminated particles that remain in the hydrocyclone underflow especially for above contaminated soils.
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