Characteristics of a rectangular fluidized bed electrode with solid copper particles or copper-coated glass particles were studied, using the electrodeposition of copper from aqueous CuSO
4-H
2SO
4 solutions. The experiments were carried out over a CuSO
4 concentration range of 0.01 to 0.05 mol/
l, a H
2SO
4 concentration range of 0.1 to 1.0 mol/
l, and a bed expansion range of 10 to 35%. The diameter of solid copper particles and copper-coated glass particles was in the range of 120 to 670 μm and 790 to 1, 030 μm, respectively.
Results show that the rate of charge transfer in the fluidized bed electrode depends on the electrode reaction rate, the effective specific resistance of solution phase, and the effective specific resistance of particle phase, ρ
m. The value of ρ
m is independent of CuSO
4 concentration and H
2SO
4 concentration, but increases with increase in bed expansion. The dependence of ρ
m on bed expansion for solid copper particles is larger than that for coppercoated glass particles. Current efficiencies in these experiments were greater than 90 %.
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