The chemical weathering of minerals and elemental mobility in Andisol that has formed during the last 6,000 years were investigated based on chemical analyses of primary minerals and clay minerals, bulk composition, and dissolution kinetics-fluid flow coupling model.
The order of Al-normalized values of major elements during the weathering is Na<Ca<K<Mg<P<Si<Ti=Fe<Al<Mn. Mobility of Na, Ca and Mg due to the dissolution of feldspar and olivine was larger than other elements, that was caused by higher solubility and dissolution rate of these minerals, while those of Si, Fe, and Al were smaller, that was resulted from the precipitations of these elements as allophane, halloysite and Fe-oxyhydroxide. The variation trend of Si, Al, and Fe contents of fine-grained materials less than 2μm in grain size with depth suggests that they are allophane, halloysite and Fe-oxyhydroxide.
The change in the amount of Ca·Na-feldspar with depth was calculated based on the dissolution kinetics-fluid flow coupling model to estimate dissolution rate of Ca·Na-feldspar. kA/M (k: rate constant, A: surface area, M: mass of fluids) is estimated to be 10
−10.3±0.5(mol/s·kgH
2O) by comparing the calculation result and the observed change in the amount of Ca·Na-feldspar with depth. Experimental dissolution rate constant for Ca·Na-feldspar, k (10
−11~10
−12), is similar to the value of the rate constant (10
−12.0±0.5) estimated from the calculation when A/M is 45 which was estimated from the grain size distribution of feldspar.
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