This paper reviews recent research on geochemical processes related to CO
2 sequestration in geological formations. Injection of CO
2 into deep saline aquifers initiates a series of geochemical processes, starting with the acidification of formation water (caused by CO
2 dissolution) and resultant reactions with surrounding rocks. These processes ensure the stability of CO
2 storage through the transfer of free CO
2 phases to various less mobile phases (e.g., carbonic acids and carbonate minerals) over long time scales; however, the geochemical transformations may impact the integrity of the injection wells, and the CO
2 injection capacity of formations around the wellbore, during operations. Several approaches, using laboratory experiments, natural analogues, field demonstration tests, and numerical modeling, are available for geochemical assessments of the impacts of CO
2 injection. Among these, two- and three-dimensional reactive transport modeling are common mainstream approaches. Reactive transport modeling has contributed to an understanding of the geochemical aspects of CO
2 injection; however, the approach is plagued by uncertainties, particularly regarding the kinetics of CO
2−water−rock inter-actions. To remedy this situation and improve the reliability of modeling results, accurate data on thermodynamic and kinetic parameters, derived from laboratory and field studies, are required. Past studies have focused on assessments of geochemical processes caused by geological sequestration of CO
2. Future efforts should pay attention to active applications of these geochemical processes, to improve storage stability, economic costs, and public acceptance, and to minimize environmental impacts.
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