Synthetic conditions of PuN from carbothermic reduction of PuO
2 has been studied in a mixed 8%H
2+92%N
2 stream at a temperature range of 1, 2701, 680°C. In the course of both reactions of the carbothermic synthesis of PuN from PuO
2 and the hydrogenation of C, the vaporization loss of Pu was observed. It increased with temperature in the tem-perature range of 1, 3501, 450°C, and reached to a constant value 1.3% of total Pu in the temperature range of 1, 4501, 680°C, at which PuN was synthesized at a reaction rate of high enough. The minimum mixing ratio (C/PuO
2, mole ratio) for the formation of high purity PuN depends on temperature. The value is 2.15 for 1, 620°C and 2.35 for 1, 680°C. The oxygen and carbon impurities in the PuN obtained were found to be 0.0950.028 and 0.174.012 W/O, respectively.
抄録全体を表示