Two kinds of cesium uranates, which are often predicted by thermochemical calculations to be formed in irradiated oxide fuels with high oxygen potentials, were prepared from U
3O
8 and Cs
2CO
3 to determine the thermal expansions and the thermal conductivities. The lattice parameters of tetragonal Cs
2UO
4 and monoclinic Cs
2U
2O
7 were measured by the high-temperature X-ray diffraction method as a function of temperature. The linear thermal expansions of Cs
2UO
4 and Cs
2U
2O
7 obtained from the temperature dependencies of the lattice parameters were 1.2% and 1.1% from room temperature to 973 and 1, 073K, respectively. The thermal diffusivities of Cs
2UO
4 and Cs
2U
2O
7 were measured on the disk-shaped samples by the laser flash method as a function of temperature. The thermal conductivities were evaluated from the measured thermal diffusivities and the bulk densities, and the specific heat capacity available in literature. The thermal conductivity of Cs
2UO
4 corrected for 100%TD was 1.2W/m•K at 980K and that of Cs
2U
2O
7 was 0.94W/m•K at 1, 093K, which are about 30% and 27% of that of UO
2, respectively.
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