Reactivity of monolith Cu-exchanged chabazite (Cu-CHA) catalyst was analyzed to investigate the reaction mechanisms of ammonia selective catalytic reduction (NH
3-SCR). The reactions, namely Ammonia adsorption/desorption, NO reduction, NO
2 reduction, and NH
3 oxidation, were identified using monolithic H-CHA and Cu-CHA catalyst. A kinetic model for the steady-state NH
3-SCR over monolithic Cu-CHA has been developed based on the experimental results. The adsorption heat of NH
3 was measured by temperature programmed desorption (TPD). Arrhenius parameters for NO reduction and NH
3 oxidation were also collected using a surrogate gas bench apparatus. The model predicted the catalyst efficiencies well in various conditions.
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