Using a detailed chemical kinetic model of normal heptane, a constant-volume ignition process of a highly-diluted mixture was analyzed. When the N
2 concentration increases or the fuel concentration decreases to a considerable extent, an ignition process starting with the LTO phase indicates double peaks of heat release in the thermal ignition preparation phase. The H
2O
2 loop reactions mainly contribute to heat release in a low-temperature region of the thermal ignition preparation phase, and H + O
2 + M = HO
2 + M mainly contributes to heat release in a high-temperature region of the phase. H
2O
2 is accumulated during the LTO and NTC phases, and then drives the H
2O
2 loop reactions to increase the temperature in the thermal ignition preparation phase. When the heat capacity of a mixture per unit fuel concentration increases, H
2O
2 is consumed in a lower-temperature region, and the heat release by the H
2O
2 loop reactions stagnates at a lower temperature. Thus, a gap of heat release between the low-temperature and high-temperature regions of the thermal ignition preparation phase is generated. Because the rate of H + O
2 = OH + O cannot overtake the rate of H + O
2 + M = HO
2 + M, CO + OH = CO
2 + H proceeds slowly with H + O
2 + M = HO
2 + M in the final stage of the ignition process rather than with the branching chain reaction.
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