Urea SCR on Diesel Particulate Filter (SCR/DPF) is important technology for reduction of NOx and PM, and is required to meet the emission and fuel economy standards which are becoming more stringent in the future. However, the SCR/DPF catalyst performance deteriorates due to exposure in severe environment. In this study, to investigate the catalyst degradation mechanism, we focused on hydrothermal degradation among many factors of the SCR/DPF degradation. Several hydrothermal aging conditions were selected. NOx reaction, NH
3 and NO oxidation rates were measured and amount of ion-exchanged Cu and ionexchangeable sites were determined by H
2-TPR and
29Si NMR, respectively. We found that NOx reaction rate increased with increasing the amount of ion-exchanged Cu. At the test temperature of 400°C and over, no correlation was found between the NOx reaction rate and the amount of ion-exchanged Cu. Under the temperature conditions of 300°C or less where the diffusion has no influence on the NOx reaction rate, NOx reaction rate is proportional to the amount of ion-exchanged Cu.
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