As ammonia (NH
3) contributes to the formation of secondary particulate matter, the real-world levels of NH
3 emitted from automobiles need to be examined. However, only a few studies have reported real-world measurements of NH
3 in automobile exhaust. In this study, we developed an on-board system to measure NH
3 emissions using near-IR laser absorption spectroscopy. This system was used to measure the real-world emission level of NH
3 from both gasoline and diesel vehicles. In the case of gasoline vehicles, NH
3 was found to be emitted mainly under high-load driving conditions such as running on a highway. In the case of diesel vehicles, NH
3 was emitted just after the engine was started; after which, only low levels of NH
3 were emitted when the vehicles were running. The amount of NH
3 emitted from gasoline vehicles was found to be larger than that from diesel vehicles.
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