A detailed chemical kinetic mechanism for n-tridecane generated by KUCRS, contains 1493 chemical species and 3641 elementary reactions. Reaction paths during ignition process for n-tridecane in air computed using the detailed mechanism, were analyzed with the initial temperatures of 650 K, 850 K, and 1100 K in the τ
1 dominant, negative temperature coefficient, and non- τ
1 regions, respectively. Based on full knowledge derived from the reaction path analysis, a reduced mechanism containing 49 species and 85 reactions, was developed and validated. The reduced mechanism includes C
3H
7, C
2H
5, and CH
3 as representative fragmental alkyl radicals, C
7H
14, C
3H
6, and C
2H
4 as representative alkenes, and C
3H
7CHO and CH
2O as representative aldehydes. Ignition delay times with different initial temperatures between 600 K and 1200 K using the reduced mechanism, and their dependences on pressure and equivalence ratio agree well with those using the detailed mechanism. The profiles of fuel, CH
2O, H
2O
2, and CO concentrations agree roughly with those using the detailed mechanism.
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