In this study, NH
3 oxidation reaction over a hydrothermally aged Cu–CHA-type SCR catalyst was studied and a model for prediction of the rate constant of the NH
3 oxidation reaction over hydrothermally aged catalyst was constructed. The results show different trends of temperature dependence on the NH
3 oxidation reaction rate above 300 ℃ for catalysts with different aging time. The structural analysis of the aged catalyst revealed that the Cu
2+ and H
+ active sites primarily were affected by aging and, thus, the NH
3 oxidation reaction rate at relatively lower temperatures can be determined from the number of the active sites. In contrast, the amount of CuO and the number of Cu
2+ and H
+ active sites can be used to determine the NH
3 oxidation reaction rate at higher temperatures.
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