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Volume 30 (2003)
- Issue 5 Pages 224-
- Issue 4 Pages 154-
- Issue 3 Pages 98-
- Issue 2 Pages 54-
- Issue 1 Pages 2-
Volume 30, Issue 2
Displaying 1-7 of 7 articles from this issue
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Yoshikata Koga2003 Volume 30 Issue 2 Pages 54-65
Published: March 30, 2003
Released on J-STAGE: September 07, 2009
JOURNAL FREE ACCESSOur thermodynamic studies on Mixing Schemes operating in aqueous solutions of nonelectrolytes are reviewed. We use the data of higher order of G than hitherto utilized. Generally there are three distinctively different Mixing Schemes present over the entire composition range. Some details of each Mixing Schemes are described as much as known at this time. The findings by other techniques are also discussed where applicable.View full abstractDownload PDF (1810K) -
Masaharu Ohba2003 Volume 30 Issue 2 Pages 66-75
Published: March 30, 2003
Released on J-STAGE: September 07, 2009
JOURNAL FREE ACCESSIf we want to get the deep understandings for the behavior of thermodynamic quantities of solutions in connection with its microscopic structure, we must proceed to the collaboration of experimental study with theoretical ones. In this article, the outline of the integral equation theory of solutions is described, because the integral equation theory is the representative theory to describe the structure and thermodynamic properties of solutions on the same theoretical bases. At first, the basic properties of distribution functions are discussed. Next, the relations of thermodynamic quantities with the distribution functions and the integral equations on the distribution functions are summarized. Finally, calculated results are shown in the cases of excess enthalpies and partial molar enthalpies of binary mixtures as an example of an attempt to construct the intuitive image for the behavior of solutions on the rigorous theoretical basis.View full abstractDownload PDF (1810K) -
Gerald R. Van Hecke, Robert A. Westervelt2003 Volume 30 Issue 2 Pages 76-84
Published: March 30, 2003
Released on J-STAGE: September 07, 2009
JOURNAL FREE ACCESSRayleigh light scattering ratios obtained using a laser light source, combined with molar volume and refractive index measurements, were used to evaluate the excess Gibbs potentials of mixing in binary liquid mixtures. When these quantities are measured as functions of temperature, as well as composition, the excess enthalpy and entropy of the binary mixtures can be obtained. This contribution presents the pertinent experimental techniques and data analyses necessary to extract excess Gibbs potentials from light scattering measurements. Data is presented for one representative system consisting of toluene and propan-2-ol mixtures.View full abstractDownload PDF (1381K) -
Hidehiro Takahashi, Chiho Yamaguchi, Yoshikazu Nishiyama2003 Volume 30 Issue 2 Pages 85-86
Published: March 30, 2003
Released on J-STAGE: September 07, 2009
JOURNAL FREE ACCESSDownload PDF (277K) -
Jun Magoshi, Hirohisa Yoshida, Han Zhang2003 Volume 30 Issue 2 Pages 87-88
Published: March 30, 2003
Released on J-STAGE: September 07, 2009
JOURNAL FREE ACCESSDownload PDF (693K) -
E. Yonemochi2003 Volume 30 Issue 2 Pages 89
Published: March 30, 2003
Released on J-STAGE: September 07, 2009
JOURNAL FREE ACCESSDownload PDF (219K) -
Expectation for CalorimetryH. Hama, K. Tashiro2003 Volume 30 Issue 2 Pages 90-91
Published: March 30, 2003
Released on J-STAGE: September 07, 2009
JOURNAL FREE ACCESSDownload PDF (271K)
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