Tropospheric increment of N
2O is of great concern in global warming issue and stratospheric ozone chemistry, which is largely attributed to the human-induced alteration of nitrogen cycle. Biological waste water treatment is a terminal destination of industrially fixed nitrogen as well as a hot spot for N
2O emission. The present understanding of microbial pathways suggests that N
2O is a by-product of ammonium oxidation and an obligate intermediate product of denitrification. Therefore, a conventional mass balance approach is insufficient to elucidate producing mechanisms of N
2O in common environments where coupling of nitrification and denitrification occurs. In this context, we proposed the measurement of natural abundance of nitrogen and oxygen isotopes to be applied for analysis of N
2O dynamics in a waste water treatment facility, and discussed future perspective of the technique.
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