The mixture of FeS, NaCl was roasted at various temperature from 300°C to 600°C in N
2atomosphere, and then was leached with water. The soluble Fe was traces. The mixture of Fe
2O
3, NaCl, S was roasted at various temperature from 300°C to 600°C in air, and then was leached with water. The soluble Fe was traces.
The FeS was rosted at various temperature from 300°C to 600°C in air, and then was leached with water. The soluble Fe was 0.1 0.3%.
The mixture of FeS, NaCl, S was roasted at various temperature from 300°C to 600°C in air, and then was leached with water. The soluble Fe increased to 400°C, and at 450°C decreased a little, and at 500°C increased extremely, and at abovd 500°C decreased again. Namely the maximum points of solubility were shown at 400°C and 500°C. When the roasting time was varied from 10 min. to 120 min. at 400°C and 500°C, in the former case the soluble Fe increased till 30 min., and after 30 min. decreased a lithe, but in the latter case the soluble Fe increared rapidly till 30 min. and after 30 min. decreased extremely.
Reaction formula can be shown as follows:
2NaCl+r/2S
2+2O
2=Na
2SO
4+Cl
2FeS+Cl
2=FeCl
2+r/6S
6→r/2S
2…(at 400°)
FeS+3/2Cl
2=FeCl
3+r/6S
6→r/2S
2…(at 500°)
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