For the purpose of recovering effectively Be
++ which was used for SO
4- removal, the dissolution of Barium Sulfate by the mixed Ion Exchange Resins was examined.
For the Cation Exchange Resins, Styrene-Divinylbenzene type strongly acidic Resins of H form (Ca or NH
4) were used, and for the Anion Exchange Resins, strongly basic Resins, Amberlite IRA-410, of HCO
3 form which was able to be regenerated easily, were used.
Between the Cations, H
+ was most useful in point of exchange capacity and Ba
++ recovery.
When HR (100c. c. as NaR) and RHCO
3 (100c. c. as RCl) were mixed with BaSO
4 precipitates and were heated at 80°C with water bath for 4hr, about 17.6g (150mE) of BaSO
4 was dissolved perfectly.
As the mixed Resins could be separated by the difference of specific gravty, it was examined that the Cation Resins were regenerated with HCl and Ba
++ was recovered as BaCl
2 and the Anion Resins were regenerated with NH
4HCO
3 and SO
- was recovered as (NH
4)
4 SO
4.
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