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50 巻, 2 号
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藤井先生追悼・Dアミノ酸特集・総説
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胸組 虎胤2022 年 50 巻 2 号 p. 3-
発行日: 2022年
公開日: 2022/12/27
ジャーナル フリーIn the early stage after the translation from mRNA, the proteins of the terrestrial organisms are composed of L-form amino acids (L-amino acids). The homochirality of the proteins derived from L-amino acids can be changed under the various conditions. L-Amino acid residues can epimerize in the proteins to become D-amino acid residues. L-Amino acids can also racemize as the free form. D-Amino acids have been detected from many kinds of organism and in the natural environments. This paper reviews on the examples of D-amino acid formation from organisms, the chemical mechanism of racemization and epimerization, and the action of D-amino acids as well as the hydrophobicity change from the epimerization in oligopeptides.
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