New interstitial compounds Sm(Fe
11Ti)X
1-δ (X =N; δ=0.8 and X=C; δ=0.7) have been made by heating a fine powder of Sm(Fe
11Ti) in nitrogen or butane, respectively. In the nitride, there is a 3% increase in unit cell volume, approximately 10% increase in the iron moment (estimated from
57Fe Mössbauer spectra) and a 185 K increase in the Curie temperature to 769 K. The uniaxial anisotropy is destroyed, however and
A20≫10
Ka0-2 in the nitride. These effects are compared with those in R
2Fe
17 nitrides or carbides and the differences are explained qualitatively in terms of Coehoorn's model considering the configuration of interstitial atoms around thd rare earth.
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