We report the carrier-doping effects in layered manganese oxysulfides Sr
2CuMnO
3S and Sr
4Cu
2Mn
3O
7.5S
2 with a two-dimensional SrMnO
x perovskite-like layer. According to the Cu 2
p core-level x-ray photoemission spectroscopy (XPS), Cu ions of Sr
2CuMn
1-xZnO
3S and Sr
4-xLa
xCu
2Mn
3O
7.5S
2 are Cu
1+ and Cu
1+/Cu
2+, respectively. On the other hand, the Mn 2
p XPS spectra indicate that the Mn ions are Mn
3+ in mother compounds (Sr
4Cu
2Mn
3O
7.5S
2 and Sr
2CuMnO
3S), and that they are Mn
3+/Mn
4+ in Sr
2CuMn
1-xZn
xO
3S. Sr
2CuMnO
3S exhibits low- dimensional antiferromagnetic ordering at 120K, while an increase tendency of magnetic susceptibility in cooling is observed below 50 K. The antiferromagnetic order of Sr
2CUMn
1-xZn
xO
3S (
x ≤ 0.2) is destroyed by an increase in non-magnetic Zn
2+ ions, and the steepness of the increase tendency of magnetic susceptibility in cooling is also enhanced by increasing Zn
2+ ions. It is supposed that ferromagnetic and antiferromagnetic magnetic order co-exist in Sr
2CuMn
1-xZn
xO
3S. The La-doped samples Sr
4-xLa
xCu
2Mn
3O
7.5S
2 (
x ≤ 0.2) show spin-glass-like behavior below 200 K. It is ascribed to the competition between the weak ferromagnetic double exchange interaction and the antiferromagnetic super-exchange interaction.
View full abstract