It has been reported that a fraction of the ash generated by a diesel engine can pass through the diesel particulate filter (DPF), causing malfunctioning of the PM sensor. In this study, to elucidate the mechanism of the ash slip, the components of ash passing through DPF due to condensed water in exhaust were measured using a HPLC and XRD. The ash sample used in this experiment was generated by an accelerated ash formation system constructed by our own, which consisted of a diffusion flame burner. It was confirmed that the components of the generated ash using the developed system were similar to those of real-world ash accumulated in DPF. The experiments for the ash slip through DPF using the diesel engine exhaust and the generated ash were performed. The components of the slipped ash through DPF contained mainly Ca
2+ and SO
4 2-, which indicate that the CaSO
4 included in the ash dissolves in condensed water in the exhaust and passes through DPF.
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