The Magnetocrystalline anisotropy constant
Kc and the magnetostriction λ
s of a Sendust alloy in composition of 9.6% Si-5.4% Al–bal. Fe are almost equal to zero. Therefore this alloy shows high permeability, but its brittleness makes it hard to roll the alloy. With the object of developing a new alloy having higher permeability and workability, we have studied the effects of the addition of Ni as a fourth element on the magnetic properties of 6% Si-4% Al–bal. Fe alloy showing a second largest value of maximum permeability μ
m in the Fe–Si–Al system.
The experimental results obtained are summarized as follows:
(1) In the 6% Si-4% Al–bal. Fe alloy the addition of 2%–4% Ni makes the coercive force
Hc decrease and the maximum permeability μ
m increase considerably.
(2) An alloy with the composition of 3.15% Ni-5.33% Si-4.22% Al–bal. Fe was annealed at 700°C for 1 h in hydrogen and cooled to room temperature at a rate of 1.7°C/s. The magnetic properties obtained were: μ
m=56800,
Hc=7.64 A/m,
Br=0.81 T and
Kf(
Br⁄
Bm)=86.6%.
(3) The effect of magnetic field cooling is striking. By applying a magnetic field 20 Oe during cooling from 700°C to room temperature after annealing at 1250°C for 1 h in hydrogen, the magnetic properties obtained were: μ
m=165000,
Hc=2.39 A/m,
Br=0.95 T,
Bm=1.09 T and
Kf=87.5%.
(4) The value of magnetostriction λ
s, magnetic moment σ
s, Curie point
Tθ, electrical resistivity ρ and Vickers hardness Hv of the new alloy were affected considerably by the addition of 2–4% Ni.
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